Physicochemical Properties Involving SZ2

DynamicsDynamics/Enthalpies of Activation/Entropies of Activation/Free Energies of Activation/Rate Constants

Product Distributions/Stereochemistry

Thermodynamic/Thermochemical/Equilibrium Constants/Heats of Reaction/Ionization Potentials/Redox Potentials/Standard Enthalpies of Reaction/Standard Entropies of Reaction/Standard Free Energies of Reaction

Spectroscopic Properties/IR CO Stretching Frequencies/IR NO Stretching Frequencies/IR CN Stretching Frequencies/IR M-H Stretching Frequencies/NMR Chemical Shifts -Carbon/NMR Chemical Shifts -Hydrogen/NMR Chemical Shifts-Phosphorus/ NMR Chemical Shifts- Ligating atom (other)/NMR Chemical Shifts-Metal/NMR CouplingConstants H-C/NMR CouplingConstants H-P/NMR CouplingConstants C-P/NMR Coupling Constants C-Pt/NMR Coupling Constants P-Pt

Structural Properties/Bond Angles/Bond Lengths

 

Dynamics

Enthalpies of Activation

Entropies of Activation

Free Energies of Activation

Rate Constants

Property: log k for the following second order reaction

h-(C5H5)Fe(CO)(acetone)(COMe)+ +SZ2 = h-(C5H5)Fe(CO)(SZ2)(COMe)+ + acetone (Analysis)

Property: log k for the following second order reaction

h-(C5Me5)Fe(CO)(acetone)(COMe)+ +SZ2 = h-(C5Me5)Fe(CO)(SZ2)(COMe)+ + acetone (Analysis)

Product Distributions

Stereochemistry

Thermodynamic/Thermochemical

Equilibrium Constants

Heats of Reaction

Ionization Potentials

Redox Potentials

h-(C5H5)Fe(CO)(SZ2)(COMe)+ + e = h-(C5H5)Fe(CO)(SZ2)(COMe) (Analysis)

Standard Enthalpies of Reaction

Standard Entropies of Reaction

Standard Free Energies of Reaction

Spectroscopic Properties

IR CO Stretching Frequencies

IR NO Stretching Frequencies

IR CN Stretching Frequencies

IR M-H Stretching Frequencies

NMR Chemical Shifts -Carbon

NMR Chemical Shifts -Hydrogen

NMR Chemical Shifts-Phosphorus

NMR Chemical Shifts- Ligating atom (other)

NMR Chemical Shifts-Metal

NMR CouplingConstants H-C

NMR CouplingConstants H-P

NMR CouplingConstants C-P

NMR Coupling Constants C-Pt

NMR Coupling Constants P-Pt

Structural Properties

Bond Angles

Bond Lengths